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Reacting Grignard reagents with ethylene oxide is a particularly useful reaction because it produces a primary alcohol containing two more carbon atoms than the original Grignard …
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Yttrium-tantalum oxide coating is expected to become an important choice for a new generation of TBCs in the future [5].The advantages of Yttrium tantalate (YTaO 4) over …
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To address these issues, studies have employed electrode surface coating techniques. This study investigates the lithium migration mechanism within different lithium …
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Its compounds, in most of which it has valence 4, are important industrial materials. Zirconia (the oxide) is used in piezoelectric crystals (see piezoelectricity), high-frequency induction coils, …
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The oxidation kinetics of the alloys in the Zircaloy family conforms to a cyclic pattern, where a protective nanocrystalline barrier oxide film of approximately 1–3 μm builds up and …
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Zirconium and hafnium oxide films are characterized by specific electrical, optical, and chemical properties, which make them of great interest as catalysts [1], [2] and as …
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Here we report the oxide formation mechanism of a CZ1 zirconium alloy with corrosion resistance surpassing many other zirconium alloy systems, such as Zircaloy-4 and …
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Abstract. This study presents a theoretical investigation of the physical mechanisms governing small-signal capacitance in ferroelectrics, focusing on hafnium zirconium oxide (Hf 0.5 Zr 0.5 …
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Oxide nucleation, lateral growth and coalescence of oxide nuclei, followed by continued oxide-film growth (thickening), generally involve both volume and short-circuit transport of the reactants …
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In this work, through density functional theory calculations, the possible reaction pathways of ZrO 2 ALD using tetrakis (dimethylamino)zirconium (TDMAZ) and water as the …
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Here we report the oxide formation mechanism of a CZ1 zirconium alloy with corrosion resistance surpassing many other zirconium alloy systems, such as Zircaloy-4 and …
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We investigated the reaction mechanism of atomic layer deposition (ALD) of zirconium oxide (ZrO 2) by integrating experiments and calculations.
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We investigated the growth characteristics and mechanism of the ALD ZrO 2 in the temperature range of 50–275 °C. Furthermore, the evolutions of film thickness and morphology were …
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Key words: antimony adsorption; iron-zirconium oxide; performance, mechanism DOI: 10.1016/S1001-0742(11)60932-7 Introduction Due to the widespread use of antimony …
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Glass and Ceramics - Cite this article. Nosova, Z.A. On the mechanism of glaze opacification with zirconium and lead oxide.
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Here, we investigated the corrosion performance and oxide formation mechanism of the CZ1 alloy and compared it with a related Zr-1Nb-1Sn model alloy. Autoclave experiments …
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To overcome the limitations of carbon-based materials, 3D-PE materials based on metal oxides have been developed [14].Fe-based materials are particularly attractive due to …
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The oxide layer becomes porous at a critical thickness. Open porosity increases from 0.01% at 10 μm to 3% at 100 μm. Between the outer porous oxide and the metal, a dense interlayer exists.
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* Corresponding authors a Department of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul, Republic of Korea E-mail: …
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High-temperature oxidation of E110 (Zr-1%Nb) zirconium alloy in steam at Т = 1100°C to various degrees has been carried out.
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Ethylene oxide is one of the most important intermediates in the chemical industry, being used for reactions with ethylene, water, alcohols and organic acids. No general …
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A novel redox-inert metal oxide, amorphous zirconium dioxide (aZrO 2), is surprisingly capable of highly efficient decontamination through peroxymonosulfate (PMS) …
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The zirconium alloy cladding reacts with water to form a protective layer of mostly monoclinic zirconium dioxide (the protective corrosion layer) according to the reaction: (1) Z r + …
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Enhancing Paint Adhesion: Sustainable Solutions for Metal Surface Treatment Facing strict regulatory standards and growing demands for sustainability, the metal treatment …
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As a toxic element of growing environmental concern, Sb is accumulated in soil and exposed to humans as a result of artificial inputs from mining and smelting (Johnston et al., …
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What is Zirconium Oxide? Zirconium oxide, also known as zirconia or zirconium dioxide, is an advanced ceramic material used in industrial coating applications. This engineered compound combines ceramic's durability with unique …
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zirconium oxide: mechanisms and physical insights† Revanth Koduru, *a Atanu K. Saha,a Martin M. Frank b and Sumeet K. Guptaa This study presents a theoretical investigation of the …
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The high corrosion resistance of zirconium alloys results from the natural formation of a dense stable oxide on the surface of the metal. This film is self healing, it continues to grow slowly at temperatures up to approximately 550 …
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If outward metal transport is the governing mechanism during the second oxidation step performed in a pure 18 O 2 (g) atmosphere, an 18 O-rich oxide will be formed …
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11| Mater.Adv., 2025, 6, 1414€1422 † 2025 The Author(s). Published by the Royal Society of Chemistry itethis:Mater. Adv.,2025, 6,1 414 Reaction mechanism of atomic layer deposition of …
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